Catalytic fast pyrolysis is a promising way to convert lignin into fine chemicals and fuels, but current approaches lack selectivity and yield unsatisfactory conversion. Understanding the pyrolysis ...
Cyclodextrin glycosyltransferase (CGTase) is an enzyme of the α-amylase family, which uses a double displacement mechanism to process α-linked glucose polymers. We have determined two X-ray structures ...
In 1899, German chemists Adolf von Baeyer and Victor Villiger discovered a reaction of a ketone and peroxyacid to form an ester. The reaction is widely used in research and industrially—to produce the ...
The photoreaction cycle of the blue-light receptor protein BLUF domains involves forward and reverse proton-coupled electron transfer (PCET) reactions, yet a unified cross-species mechanism is lacking ...
Crystallographic studies of D-xylose isomerase (D-xylose ketol-isomerase, EC 5.3.1.5) incubated to equilibrium with substrate/product mixtures of xylose and xylulose show electron density for a bound ...
Many different mechanisms have been suggested for the oxidative lipid fragmentations that produce biologically active aldehydes such as 4-hydroxynon-2-enal (HNE), oxononanoyl phosphatidylcholine ...
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